How Self-Cleaning Fabric Works
The self-cleaning fabrics work using the photocatalytic properties of titanium dioxide, a compound used in many new nanotechnology solar cell applications.
The fabric is coated with a thin layer of titanium dioxide particles that measure only 20 nanometers in diameter. When this semi-conductive layer is exposed to light, photons with energy equal to or greater than the band gap of the titanium dioxide excite electrons up to the conduction band. The excited electrons within the crystal structure react with oxygen atoms in the air, creating free-radical oxygen. These oxygen atoms are powerful oxidizing agents, which can break down most carbon-based compounds through oxidation-reduction reactions. In these reactions, the organic compounds (i.e. dirt, pollutants, and micro organisms) are broken down into substances such as carbon dioxide and water. Since the titanium dioxide only acts as a catalyst to the reactions, it is never used up. This allows the coating to continue breaking down stains over and over.
The fabric is coated with a thin layer of titanium dioxide particles that measure only 20 nanometers in diameter. When this semi-conductive layer is exposed to light, photons with energy equal to or greater than the band gap of the titanium dioxide excite electrons up to the conduction band. The excited electrons within the crystal structure react with oxygen atoms in the air, creating free-radical oxygen. These oxygen atoms are powerful oxidizing agents, which can break down most carbon-based compounds through oxidation-reduction reactions. In these reactions, the organic compounds (i.e. dirt, pollutants, and micro organisms) are broken down into substances such as carbon dioxide and water. Since the titanium dioxide only acts as a catalyst to the reactions, it is never used up. This allows the coating to continue breaking down stains over and over.
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